Raman Spectroscopy of Medieval Manuscripts in Bulgarian National Library – Preliminary Results

Authors

  • Deyan Lesigyarski National Institute of Geophysics, Geodesy and Geography, Bulgarian Academy of Sciences, Sofia, Bulgaria
  • Iskra Tsvetanska University of Library Studies and Information Technology, Sofia, Bulgaria
  • Inna Dimitrova University of Library Studies and Information Technology, Sofia, Bulgaria

DOI:

https://doi.org/10.55630/dipp.2025.15.12

Keywords:

Raman Spectroscopy, Parchment, Manuscript, Palimpsest, XRF

Abstract

This paper presents the initial stages for preparation of a digital catalog (library), including analytical information gathered by using portable Raman spectroscopy instrument for the study of medieval parchment manuscripts from the repository of the Bulgarian National Library” Saints Cyril and Methodius”.

References

Barletta, R. E., & Roe, C. H. (2011). Differential Raman cross section of dimethyl sulfide. Journal of Raman Spectroscopy, 42, 117–121. https://doi.org/10.1002/jrs.2749

Brenner, S., & Miklas, H. (2019). Multispectral imaging of degraded manuscripts in the Ivan Vazov National Library in Plovdiv. Godišnik na Narodna biblioteka „Ivan Vazov“ (2014–2018) [ Yearbook of the Ivan Vazov National Library (2014–2018) ], 32–48.

Cappa, F., & Schreiner, M. (2019). Raman spectroscopy for the material analysis of medieval manuscripts. In Nanotechnologies and nanomaterials for diagnostic, conservation and restoration of cultural heritage.

Christova-Shomova, I. (2018). Dragotin minej. Bulgarski rukopis ot nachaloto na XII vek [ The Dragotin Menaion: Bulgarian manuscript from the beginning of the 12th century ]. University Press “St. Kliment Ohridski”.

Haralampiev, N. (2013). Dissertation abstract: Tehnika i tehnologija na ukrasata vav vizantijskite pergamentni rukopisi. Tehnologichen analiz na izborno evangelie Cod. D. Gr. 212 ot CSVP “Prof. Ivan Dujchev” [ Technique and technology of decoration in Byzantine parchment manuscripts. Technological analysis of the selected Gospel Cod. D. Gr. 212 from CSVP “Prof. Ivan Duychev” ]. https://digital.libsu.uni -sofia.bg/bg/v/3034

Malea, E., Boyatzis, S. C., Karlis, D., Boghosian, S., & Zervos, S. (2024). The complementary use of Raman, ATR-FTIR spectroscopy, and chemometrics for investigating the deterioration of artificially aged parchment. Journal of Raman Spectroscopy,, 1–15. https://doi.org/10.1002/jrs.6755

Nastova, I., Grupče, O., Minčeva -Šukarova, B., & Kostadinovska, M. (2015). Spectroscopic analysis of pigments and inks in manuscripts. III. Old-Slavonic manuscripts with multicolored rubication. Vibrational Spectroscopy, 78, 39–48. http://dx.doi.org/10.1016/j.vibspec.2015.03.005

Nastova, I., Grupče, O., Minčeva -Šukarova, B., Kostadinovska, M., Turan, S., Yaygingol, M., Ozcatal, M., Martinovska, V., & Jakovlevska-Spirovska, Z. (2011). Micro- Raman spectroscopic analysis of inks and pigments in illuminated medieval Old- Slavonic manuscripts. Journal of Raman Spectroscopy, 43, 1729–1736. https://doi.org/10.1002/jrs.4084

Retko, K., Legan, L., Kosel, J., & Ropret, P. (2024). Identification of iron gall inks, logwood inks, and their mixtures using Raman spectroscopy, supplemented by reflection and transmission infrared spectroscopy. Heritage Science, 12, 212–231. https://doi.org/10.1186/s40494 -024-01323-0

Rigante, C. L., Calvano, C. D., Ventura, G., & Cataldi, T. R. I. (2025). Look but don’t touch: Non-invasive chemical analysis of organic paint binders – A review. Analytica Chimica Acta, 1335, 343251. https://doi.org/10.1016/j.aca.2024.343251

Downloads

Published

2025-09-05

How to Cite

Lesigyarski, D., Tsvetanska, I., & Dimitrova, I. (2025). Raman Spectroscopy of Medieval Manuscripts in Bulgarian National Library – Preliminary Results. Digital Presentation and Preservation of Cultural and Scientific Heritage, 15, 129–136. https://doi.org/10.55630/dipp.2025.15.12